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Table 7 Major hydroperoxides emitted during autoxidation of methyl oleate, linoleate and linolenate (Gunstone 1996 )

From: Low temperature oxidation of linseed oil: a review

Methyl ester

Position of OOH

Position of double bond

Configuration

Yielda(%)

Oleate

8

9

cis or trans

27

 

9

10

mainly trans

24

 

10

8

mainly trans

23

 

11

9

cis or trans

26

Linoleate

9

10, 12

trans, cis, conjugated diene

52

 

13

9, 11

cis, trans, conjugated diene

48

Linolenate

9

10,12,15

conjugated diene

32

 

12

9, 13, 15

conjugated diene, can form cyclic peroxide

11

 

13

9, 11, 15

conjugated diene, can form cyclic peroxide

11

 

16

9, 12, 14

conjugated diene

46

  1. aYields are calculated from total mono-hydroperoxides only.